μ-1,6,7,12-Tetraazaperylene-κ4N1,N12:N6,N7-bis[chlorido(η6-p-cymene)ruthenium(II)] bis(hexafluoridophosphate) acetone disolvate
نویسندگان
چکیده
منابع مشابه
μ-1,2-Bis(diphenylphosphino)ethane-κ2 P:P′-bis{[1,2-bis(diphenylphosphino)ethane-κ2 P,P′]bromidocopper(I)} acetone disolvate
In the crystal structure of the title compound, [Cu(2)Br(2)(dppe)(3)]·2CH(3)COCH(3) [dppe is 1,2-bis-(diphenyl-phosphino)-ethane, C(26)H(24)P(2)], the two Cu centers are bridged by a dppe ligand and each metal center carries one chelating dppe unit, with the fourth coordination site available for the Br(-) anion. The mol-ecule is centrosymmetric, with the center of symmetry located between the ...
متن کاملS)ruthenium(II)] dihydrate acetone disolvate
Author(s) of this paper may load this reprint on their own web site provided that this cover page is retained. Republication of this article or its storage in electronic databases or the like is not permitted without prior permission in writing from the IUCr.
متن کاملDi-μ-methoxido-μ-oxido-bis[triphenylantimony(V)] methanol disolvate
The title compound, [Sb(2)(C(6)H(5))(6)(CH(3)O)(2)O]·2CH(3)OH, is the methanol disolvate of a dinuclear triphenyl-anti-mony derivative. The mol-ecule shows C(s) symmetry. The Sb-O-Sb angles cover a range from 89.65 (10)° to 102.08 (13)°. In the crystal structure, two O-H⋯O hydrogen bonds are present.
متن کاملμ-1,6,7,12-Tetraazaperylene-κ4 N 1,N 12:N 6,N 7-bis[chlorido(η6-p-cymene)ruthenium(II)] bis(hexafluoridophosphate) acetone disolvate
In the title compound, [Ru2(C10H14)2Cl2(C16H8N4)](PF6)2·2C3H6O, the binuclear Ru(II) complex dication, [{RuCl(η(6)-cym)}2(μ-tape)](2+), built up by a planar 1,6,7,12-tetra-aza-perylene (tape) bridge, two η(6)-bound cymene (cym) ligands and two chloride ligands, includes an inversion center. The Ru(II) atom shows the typical piano-stool motif for arene coordination. The counter-charge is provide...
متن کامل1,1,2,2-Tetrakis(dimethylamino)ethane-1,2-diium bis(tetraphenylborate) acetone disolvate
The title compound, C(10)H(24)N(4) (2+)·2C(24)H(20)B(-)·2C(3)H(6)O, crystallizes with two acetone solvent mol-ecules per asymmetric unit. In the dication, both amidinium units are twisted about the central C-C single bond by 63.8 (3)° and the positive charges are delocalized over both N-C-N planes.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2014
ISSN: 1600-5368
DOI: 10.1107/s160053681400035x